Investigation on the anti-reduction mechanism of Ti4+ in high dielectric constant system Ca0.9La0.067TiO3 by doping with Al2O3

Ca_0.9La_0.067TiO₃ (abbreviated as CLT) ceramics doped with different amount of Al₂O₃ were prepared via the solid state reaction method. The anti-reduction mechanism of Ti⁴⁺ in CLT ceramics was carefully investigated. X-ray diffraction (XRD) was used to analyze the phase composition and lattice structure. Meanwhile, the Rietveld method was taken to calculate the lattice parameters. X-ray photoelectron spectroscopy (XPS) was employed to study the valence variation of Ti ions in CLT ceramics without and with Al₂O₃. The results showed that Al³⁺ substituted for Ti⁴⁺ to form solid solution and the solid solubility limit of Al³⁺ is near 1.11 mol%. Furthermore, the reduction of Ti⁴⁺ in CLT ceramics was restrained by acceptor doping process and the Q × f values of CLT ceramics were improved significantly. The CLT ceramic doped with 1.11 mol% Al₂O₃ exhibited good microwave dielectric properties: ε_r = 141, Q × f = 6848 GHz, τ_f = 576 ppm/°C.     

Simultaneous determination of synthetic food additives in kimchi by liquid chromatography-electrospray tandem mass spectrometry

Food Science and Biotechnology - A new analytical method was developed for the simultaneous determination of seven food additives (Ponceau 4R, Allura Red AC, Amaranth, 4-hydroxymethyl benzoic acid,...     

疏水引力在煤泥浮选过程中的作用机理及应用

为了分析疏水引力在煤泥浮选过程中的作用机理,将-0.074mm的不同密度细粒煤泥混入粗粒煤泥中进行浮选试验,研究不同密度细粒煤泥对可燃体回收率的影响;进行了EDLVO理论计算,分析各作用能的作用效果和疏水引力的成因。结果表明:1.3～1.4 g/cm~3密度级细粒煤泥容易罩盖于粗粒精煤表面疏水部分;水中两个相互接近的疏水表面间的作用以疏水作用为主,疏水引力的产生是由于水中疏水表面相互接近到一定距离时自发形成了纳米气泡桥;浮选调浆的强度应适中,在破坏煤泥颗粒间疏水引力的同时而不破坏煤泥与气泡的附着。     

基于信息熵—集对分析的煤矿隐患排查治理风险评估模型

以煤矿安全隐患排查治理风险为研究对象，分析隐患排查闭环管理全过程，并基于此建立了隐患排查治理能力纵向评估指标体系，融合熵值法和集对分析理论，建立了煤矿安全隐患排查治理风险纵向评估模型，为企业更好地了解自身隐患排查治理能力及变化发展趋势提供参考，最后进行了实例分析。     

Contrastive analysis of cooling performance between a high-level water collecting cooling tower and a typical cooling tower

A three-dimensional (3D) numerical model is established and validated for cooling performance optimization between a high-level water collecting natural draft wet cooling tower (HNDWCT) and a usual natural draft wet cooling tower (UNDWCT) under the actual operation condition at Wanzhou power plant, Chongqing, China. User defined functions (UDFs) of source terms are composed and loaded into the spray, fill and rain zones. Considering the conditions of impact on three kinds of corrugated fills (Double-oblique wave, Two-way wave and S wave) and four kinds of fill height (1.25 m, 1.5 m, 1.75 m and 2 m), numerical simulation of cooling performance are analysed. The results demonstrate that the S wave has the highest cooling efficiency in three fills for both towers, indicating that fill characteristics are crucial to cooling performance. Moreover, the cooling performance of the HNDWCT is far superior to that of the UNDWCT with fill height increases of 1.75 m and above, because the air mass flow rate in the fill zone of the HNDWCT improves more than that in the UNDWCT, as a result of the rain zone resistance declining sharply for the HNDWCT. In addition, the mass and heat transfer capacity of the HNDWCT is better in the tower centre zone than in the outer zone near the tower wall under a uniform fill layout. This behaviour is inverted for the UNDWCT, perhaps because the high-level collection devices play the role of flow guiding in the inner zone. Therefore, when non-uniform fill layout optimization is applied to the HNDWCT, the inner zone increases in height from 1.75 m to 2 m, the outer zone reduces in height from 1.75 m to 1.5 m, and the outlet water temperature declines approximately 0.4 K compared to that of the uniform layout.     

Test sample allocation method for testability verification test

An extended failure mode effect and criticality analysis (FMECA)-based sample allocation method for testability verification is presented in this study to deal with the poor representativeness of test sample sets and the randomness of the testability evaluation results caused by unreasonable selection of failure samples. First, the fault propagation intensity is introduced as part of the extended information of FMECA, and the sample allocation impact factors of component units and failure modes are determined under this framework. Then, the failure mode similarity and impact factor support are defined, and the game decision method for weighing the relationship between similarity and support is proposed to obtain the weight of failure mode impact factor. Finally, a two-step allocation framework of test samples is formulated to realize the sample allocation of component units and failure modes. This method is applied to the testability verification test of a launch control system. Results show that this method can obtain more representative test samples compared with the traditional sample allocation method while effectively reducing randomness of single testability evaluation result.     

An Artificial Skyrmion Platform with Robust Tunability in Synthetic Antiferromagnetic Multilayers

Magnetic skyrmions are topologically nontrivial spin structures, and their existence in ferromagnetically coupled multilayers has been widely reported with a disordered arrangement. Here, a nucleation scenario of ordered skyrmions in nanostructured synthetic antiferromagnetic (SAF) multilayers is proposed and experimentally demonstrated using direct magnetization imaging, indirect magnetometer and magnetoresistance measurement, and micromagnetic simulation. Instead of relying on Dzyaloshinskii–Moriya interaction, the antiferromagnetic interlayer exchange coupling in the SAF multilayers fulfills the role of nucleation and stabilization of skyrmions. The robustness of the proposed skyrmion nucleation scenario is examined against temperature from 4.5 to 300 K and device size from 400 to 1200 nm. Interestingly, these synthetic skyrmions still behave well with a size less than 100 nm. The higher stability than generic magnetic domains can be attributed to topological protection. The results thus provide an artificial skyrmion platform to meet the functional needs of high density and designable arrangement in magnonic and spintronic applications.     

Gel Polymer Electrolyte with Anion‐Trapping Boron Moieties via One‐Step Synthesis for Symmetrical Supercapacitors

A novel gel polymer electrolyte (GPE) which is based on new synthesized boron‐containing monomer, benzyl methacrylate, 1 m LiClO₄/N,N‐dimethylformamidel liquid electrolyte solution is prepared through a one‐step synthesis method. The boron‐containing GPE (B‐GPE) not only displays excellent mechanical behavior, favorable thermal stability, but also exhibits an outstanding ionic conductivity of 2.33 mS cm^?1 at room temperature owing to the presence of anion‐trapping boron sites. The lithium ion transference in this gel polymer film at ambient temperature is 0.60. Furthermore, the symmetrical supercapacitor which is fabricated with B‐GPE as electrolyte and reduced graphene oxide as electrode demonstrates a broad potential window of 2.3 V. The specific capacitance of symmetrical B‐GPE supercapacitors retains 90% after 3000 charge–discharge cycles at current density of 1 A g^?1.     

Detecting Cysteine in Bioimaging with a Near-Infrared Probe Based on a Novel Fluorescence Quenching Mechanism

Near-infrared (NIR) fluorescent probes are very significant for detecting cysteine in biological systems. Herein, we report a highly selective and sensitive NIR turn-on fluorescent probe (BDP-NIR) based on BODIPY with large Stokes shift (105 nm) for detecting Cys. We clarified the sensing mechanism based on the different thiol-induced S_NAr substitution/rearrangement reaction of the probe with cysteine and homocysteine/glutathione, which leads to the corresponding amino- and thiol-BODIPY dyes with distinct photophysical properties. Moreover, a novel mechanism of fluorescence quenching was demonstrated by density functional theory calculation. The reason for the fluorescence quenching of the probe might be intersystem crossing (from singlet to triplet excited state). Moreover, BDP-NIR had a high linear dynamic range of 0–500 μM, which was promising for detecting cysteine quantificationally. Significantly, BDP-NIR was capable of sensing endogenous cysteine in living cells and in vivo.